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Two different gases. One identical reading.each takes oxygen from the hot surface and hands electrons back to the grainthe gas you wanttakes an oxygenleaves with itelectrons flow back into the graina different moleculetakes an oxygenleaves with itelectrons flow back into the grain≠resistanceresistance=The sensor cannot tell them apart. That is the problem worth solving.

There are many ways to detect a gas: electrochemical cells, infrared absorption, catalytic beads, photoionisation. Each has its place. The most common is the metal-oxide sensor, because it is cheap, small, rugged, and consumes nothing in order to work.

It is also unselective. A great many gases move the reading, and the reading looks the same whichever one caused it.


What we are doing about it

Historically, improving a sensor has meant trying formulations until something works: which oxide, which metal is added to it, how much of it, how hot it is fired and for how long. Most of those choices are inherited rather than reasoned.

We work the problem from the other end, computing the surface chemistry itself so that the choice of oxide, dopant and firing follows from the physics rather than from precedent. The aim is a sensor designed for its target.

The work is aimed at arrays built for one detection problem at a time.

How a gas sensor actually works

We have mapped every path a molecule can take when it meets a hot metal-oxide surface, including all the ones that dead-end.

What a metal-oxide sensor is made ofnot a component: a recipe, printed and bakedthe oxidetin, zinc or tungstenalmost all of ita trace of metalpalladium, platinumor gold: a smallfraction by weightglass fritso the film stayson the substrateand organicsa binder and a liquidto print it. They burnaway and leaveporositythe filmthen fired:the next slideFour ingredients. Every one of them is a decision, and they interact.
What the atlas coversfour things have to happen in order. Miss one and the gas is never detectedit arrives and sticksa hot surface, and amolecule that stays on itit burns on the spotthe surface's own oxygenis what burns itthe surface clearsair puts that oxygen back,unless water got there firstthe grains report itin clean airwith the gaselectrons come back, andthe resistance changesPART ONEevery road one molecule can take through those four, including the many that dead-endPART TWOwhat those dead ends force you to make: the oxide, the metal, the heat, the firingA material that fails any one of these is no use as a sensor.

The full set is available to researchers on request. brett@sniffi.ai

Contact

Name
Brett Ottolenghi
Role
Founder
Email
brett@sniffi.ai